Consider this system at equilibrium.
A(aq)<−−−>B(aq)deltaH=−750kJ/mol

What can be said about Q and K immediately after an increase in temperature?
A) Q>K because Q increased
B) Q>K because K decreased
C) Q D) Q E) Q=K because neither charged

How will the system respond to a temperature increase?
A) shift left
B) shift right
C) no change

Respuesta :

Answer:

a) Q>K because K decreased

b) shift left

Explanation:

According to Van't Hoff equation

d (ln K)/ dT = ΔH/RT²

since ΔH< 0 (exothermic reaction) , then d (ln K)/ dT < 0 → K decreases with an increase in temperature

thus

a) Since Q represents the product of concentrations , and assuming an increase in temperature do not affect significantly the concentration of products in a liquid state , then Q remains approximately constant , but K decreases → Q>K because K decreased

( thus ΔG is positive and ΔG is negative for the reverse reaction → products will produce reactants until the new equilibrium is reached)

b) Since K decreased , the system will shift towards the reactants and thus it  will shift to the left