A 2.00-L glass soda bottle filled only with air is tightly capped at 25°C and 728.0 mmHg. If the bottle is placed in water at 65°C, what is the pressure in the bottle?

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Answer:

The pressure in the bottle is 826 mmHg

Explanation:

In this case it is assumed that the volume of the soda bottle does not change, so it remains constant with a value of 2.00 L. Then it is possible to apply the Gay Lussac law.

This law indicates that when there is a constant volume, as the temperature increases, the gas pressure increases. And when the temperature decreases, gas pressure decreases. That is, the gas pressure is directly proportional to its temperature.

Gay-Lussac's law can be expressed mathematically as follows:

[tex]\frac{P}{T}=k[/tex]

Where P = pressure, T = temperature and K = Constant

Having a gas that is at a pressure P1 and a temperature T1, as the temperature varies to a new T2 value, then the pressure will change to P2. It is then fulfilled:

[tex]\frac{P1}{T1} =\frac{P2}{T2}[/tex]

Remember that the temperature must be in degrees Kelvin (° K) and that 0 ° C is 273.15 ° K

In this case you know:

  • P1= 728 mmHg
  • T1= 25°C+273.15°K= 298.15°K
  • P2= ?
  • T2= 65°C+273.15°K= 338.15°K

Replacing:

[tex]\frac{728 mmHg}{298.15K} =\frac{P2}{338.15K}[/tex]

Resolving you get:

[tex]\frac{728 mmHg}{298.15K} *338.15K=P2[/tex]

P2=825.67 mmHg≅826 mmHg

The pressure in the bottle is 826 mmHg

The pressure of the bottle is 825.7 mmHg

The parameters given in the question are

Pressure 1= 728 mmHg

Temperature 1= 25°C

= 25+273

T1= 298K

Temperature 2= 65°C

= 65 +273

= 338K

P1/T1= P2/T2

728/298= P2/338

Cross multiply

298 × P2= 728 × 338

298 × P2= 246,064

P2= 246,064/298

P2= 825.7

Hence the pressure in the bottle is 825.7 mmHg

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