A technician plates a faucet with 2.68 g of Cr metal by electrolysis of aqueous Cr2(SO4)3. If 15.2 min is allowed for the plating, what current is needed? Use 96500 C/mol e- for the Faraday constant. Enter a number to 2 decimal places.

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Answer:

16.36A

Explanation:

We'll begin by writing a balanced dissociation equation of aqueous Cr2(SO4)3. This is illustrated below:

Cr2(SO4)3 —> 2Cr^3+ 3(SO4)^2-

From the above, we can see that Cr is trivalent.

Next, let us determine the number of faraday needed to deposit metallic Cr. This is illustrated below:

Cr^3+ 3e- —> Cr

From the above equation, 3 faradays are needed to deposit metallic Cr

1 faraday = 96500C

Therefore, 3 faraday = 3 x 96500C = 289500C.

Molar Mass of Cr = 52g/mol

Now let us determine the quantity of electricity needed for 2.68g of Cr metal

This is shown below:

52g of Cr required 289500C.

Therefore, 2.68g of Cr will require = (2.68 x 289500)/52 = 14920.38C

Now, with this quantity of electricity (i.e 14920.38C), we can easily calculate the current needed for the process. This is illustrated below:

Q (quantity of electricity) = 14920.38C

t (time) = 15.2mins = 15.2 x 60 = 912secs

I (current) =?

Apply the equation Q = It

Q = It

14920.38 = I x 912

Divide both side by 912

I = 14920.38/912

I = 16.36A

Therefore, a current of 16.36A is needed for the process.

The current needed is 16.36 A. The quantity of electricity (i.e 14920.38C), we can easily calculate the current needed for the process.

Balanced dissociation equation:

[tex]Cr_2(SO_4)_3 ---- > 2Cr^{3+}+ 3SO_4^{2-}[/tex]

The number of faradays needed to deposit metallic Cr. This is illustrated below:

[tex]Cr^{3+}+ 3e^- ---- > Cr[/tex]

Given:

3 faradays are needed to deposit metallic Cr

1 faraday = 96500C

Therefore, 3 faraday = 3 * 96500C = 289500C.

Molar Mass of Cr = 52g/mol

52g of Cr required 289500C.

Therefore, 2.68g of Cr will require = (2.68 * 289500)/52 = 14920.38C

Now, with this quantity of electricity (i.e 14920.38C), we can easily calculate the current needed for the process. This is illustrated below:

Q (quantity of electricity) = 14920.38C

t (time) = 15.2mins = 15.2 x 60 = 912secs

To find:

I (current) =?

Apply the equation,

Q = It

14920.38 = I * 912

I = 14920.38/912

I = 16.36A

Therefore, a current of 16.36A is needed for the process.

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