Answer:
Because the intermolecular interactions are weaker.
Explanation:
Nonpolar substances do not have dipole-dipole or hydrogen bond interactions, which are strong intermolecular interactions that often make the substance liquid or solid. Instead, they must rely on van der Waals forces, which are relatively weaker interactions that are often insufficient to hold the molecules together in liquid or solid form.
The magnitude of intermolecular association in nonpolar substance is much lower than the magnitude of intermolecular association in polar substances.
Polar substances are those substances in which a permanent dipole exists in the molecule. In a molecule having a permanent dipole, the electronegativity difference between the atoms bonded in the molecule is high.
As a result of this high electronegtivity difference between atoms, the molecules interact more intimately hence polar molecules tend to exist mostly as liquids and gases while nonpolar molecules having less intimate intermolecular interaction via dispersion forces exist mostly as gases.
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