First, remembering Snell's law, we know that:
[tex]sin(\theta)=\frac{n_{entering}}{n_{leaving}}[/tex]So, we know that n_entering is 1.33, as the ray is entering water, and we have the angle, thus:
[tex]sin(69.30°)=\frac{1.33}{n_{leaving}}[/tex]And therefore:
[tex]n_{leaving}=\frac{1.33}{sin(69.30°)}=1.42[/tex]