The acid-dissociation constants of sulfurous acid (h2so3) are kal = 1.7 × 10-2 and ka2 = 6.4 × 10-8 at 25.0°c. calculate the ph of a 0.163 m aqueous solution of sulfurous acid.

Respuesta :

Constructing the ICE table for acid-dissociation  of sulfurous acid

 H₂SO₃ --> H⁺ + HSO₃⁻

I    0.163 M      0        0

C     - x           + x       + x

E   0.163 - x    + x       + x

Writing the acid dissociation expression  of sulfurous acid,

Kₐ = [H⁺ ][ HSO₃⁻]/ [H₂SO₃]

Plugging in the values we get,

\frac{x²}{(0.163 - x)} = 1.7 x 10⁻²

Since 1.7 x 10⁻² is small we can ignore x in the denominator,

\frac{x²}{0.163}  = 1.7 x 10⁻²

x = 0.052640 M  

pH = 1.28  

Thus the pH of a 0.163 M aqueous solution of sulfurous acid is 1.28.

The ph of a 0.163 m aqueous solution of sulfurous acid is:

  • 1.28

What is an Aqueous Solution?

This refers to type of solution which has a high solubility in water.

To find the ph of a 0.163 m aqueous solution of sulfurous acid, we would have to:

First construct the ICE table

  • H₂SO₃ --> H⁺ + HSO₃⁻

  • I    0.163 M      0        0

  • C     - x           + x       + x

  • E   0.163 - x    + x       + x

Next, we would have to express the acid dissociation of sulfurous acid:

[tex]Kₐ = [H⁺ ][ HSO₃⁻]/ [H₂SO₃][/tex]

Next, we input the values

{x²}{(0.163 - x)} = 1.7 x 10⁻²

Expand further

{x²}{0.163}  = 1.7 x 10⁻²

x = 0.052640 M  

pH = 1.28 .

Read more about aqueous solution here:
https://brainly.com/question/12406565